Fundamentos de electroquimica y corrosion

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© 2000 ASM International. All Rights Reserved. Fundamentals of Electrochemical Corrosion (#06594G)

www.asminternational.org

Fundamentals of Electrochemical Corrosion
E.E. Stansbury
Professor Emeritus Department of Materials Science and Engineering The University of Tennessee and

R.A. Buchanan
Robert M. Condra Professor Department of Materials Science and Engineering The University ofTennessee

ASM International Materials Park, Ohio 44073-0002 www.asminternational.org

© 2000 ASM International. All Rights Reserved. Fundamentals of Electrochemical Corrosion (#06594G)

www.asminternational.org

Copyright © 2000 by ASM International® All rights reserved No part of this book may be reproduced, stored in a retrieval system, or transmitted, in any form or by any means,electronic, mechanical, photocopying, recording, or otherwise, without the written permission of the copyright owner. First printing, July 2000
Great care is taken in the compilation and production of this book, but it should be made clear that NO WARRANTIES, EXPRESS OR IMPLIED, INCLUDING, WITHOUT LIMITATION, WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE, ARE GIVEN IN CONNECTIONWITH THIS PUBLICATION. Although this information is believed to be accurate by ASM, ASM cannot guarantee that favorable results will be obtained from the use of this publication alone. This publication is intended for use by persons having technical skill, at their sole discretion and risk. Since the conditions of product or material use are outside of ASM’s control, ASM assumes no liability orobligation in connection with any use of this information. No claim of any kind, whether as to products or information in this publication, and whether or not based on negligence, shall be greater in amount than the purchase price of this product or publication in respect of which damages are claimed. THE REMEDY HEREBY PROVIDED SHALL BE THE EXCLUSIVE AND SOLE REMEDY OF BUYER, AND IN NO EVENT SHALLEITHER PARTY BE LIABLE FOR SPECIAL, INDIRECT OR CONSEQUENTIAL DAMAGES WHETHER OR NOT CAUSED BY OR RESULTING FROM THE NEGLIGENCE OF SUCH PARTY. As with any material, evaluation of the material under end-use conditions prior to specification is essential. Therefore, specific testing under actual conditions is recommended.

Nothing contained in this book shall be construed as a grant of any right ofmanufacture, sale, use, or reproduction, in connection with any method, process, apparatus, product, composition, or system, whether or not covered by letters patent, copyright, or trademark, and nothing contained in this book shall be construed as a defense against any alleged infringement of letters patent, copyright, or trademark, or as a defense against liability for such infringement.Comments, criticisms, and suggestions are invited, and should be forwarded to ASM International. ASM International staff who worked on this project included Veronica Flint, Manager of Book Acquisitions; Scott Henry, Assistant Director, Reference Publications; Bonnie Sanders, Manager of Production; Carol Terman, Copy Editor; Kathleen Dragolich, Production Supervisor; and Alexandru Popaz-Pauna, BookProduction Coordinator. Library of Congress Cataloging-in-Publication Data Stansbury, E.E. Fundamentals of electrochemical corrosion / E.E. Stansbury and R.A. Buchanan p. cm. 1. Electrolytic corrosion. 2. Corrosion and anti-corrosives. I. Buchanan, R.A. (Robert Angus), 1930II. Title. TA462.S714 2000 620.1′1223—dc21 99-058428 ISBN: 0-87170-676-8 SAN: 204-7586 ASM International® Materials Park, OH44073-0002 www.asm-intl.org Printed in the United States of America Cover art represents autocatalytic processes occurring in a corrosion pit. The metal, M, is being pitted by an aerated NaCl solution. Rapid dissolution occurs within the pit, while oxygen reduction takes place on the adjacent surfaces. Source: U.R. Evans, Corrosion, Vol 7 (No. 238), 1951

© 2000 ASM International. All Rights...
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