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Dark Beginning 1 - Available from the start
Dark Beginning 2 - Available from the start
Dark Revelation Volume 1 - Available from the start
Dark Revelation Volume 2 - Available from the startSoul of the Duelist - Start Chapter II
Rise of Destiny - 50 single duels
Flaming Eternity - Get the parts for Toru in Chapter II
The Lost Millenium - Defeat Bronson, Minegishi, Gemma, Virgil, Zeruga,Scotch, and Clint 3 times each
Cybernetic Revolution - Duel Jack in Chapter II
Elemental Energy - 100 single duels
Shadow of Infinity - Start Chapter III
Enemy of Justice - Defeat Reimi, Lillie,Hayakawa, Masaki, Gordon, and Kuroe 3 times each
Power of the Duelist - Start Chapter III
Cyberdark Impact - 200 single duels
Strike of Neos - Duel Virgil in Chapter III
Force of the Breaker -Defeat Rossi, Kazuhiro, Honda, Yanagigaura, Helio, Angie, Nelson, Figaro, and Corse 3 times each.
Tactical Evolution - Start Chapter IV
Gladiator's Assault - (Can't read this, but it's defeating morepeople 3 times each)
Light of Destruction - Defeat Lazar, Sherry, and Elsworth 3 times each
The Duelist Genesis - Start Chapter VI
Crossroads of Chaos - Start Chapter V
Crimson Crisis - Start thefinal chapter
Raging Battle - Clear the side event where you defeat Team Satisfaction (the Enforcers) in a race.
Ancient Prophecy - Defeat Torunka and Regulus 3 times each
Stardust Overdrive - Cleara side event in which you duel 3 members of Team 5Ds in Rental Duels
Absolute Powerforce - Win 3 consecutive Rental Duels in the Daimon Area
The Shining Darkness - Defeat Nico, West, Sergio,Barbara, and one other person 3 times each
Duelist Revolution - Defeat Andre in the final chapter
Starstrike Blast - Defeat Yusei, Jack, and Crow, 3 times each in single duels, Tag Duels, and Tag TurboDuels.
Storm of Ragnarok - Defeat Team Ragnarok 3 times each in single duels, Tag Duels, and Tag Turbo Duels
Synchro, Awaken!! - Available from the start
Invasion of Worms!! - Available from the...