Manual Ing Quimico

Section 2

Physical and Chemical Data*

Bruce E. Poling Department of Chemical Engineering, University of Toledo (Physical and Chemical Data) George H. Thomson AIChE Design Institute for Physical Properties (Physical and Chemical Data) Daniel G. Friend National Institute of Standards and Technology (Physical and Chemical Data) Richard L. Rowley Department of Chemical Engineering, BrighamYoung University (Prediction and Correlation of Physical Properties) W. Vincent Wilding Department of Chemical Engineering, Brigham Young University (Prediction and Correlation of Physical Properties)

GENERAL REFERENCES PHYSICAL PROPERTIES OF PURE SUBSTANCES Tables 2-1 2-2 Physical Properties of the Elements and Inorganic Compounds . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . . . . Physical Properties of Organic Compounds . . . . . . . . . . . . . . 2-7 2-28

2-10

Vapor Pressures of Organic Compounds, up to 1 atm . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

2-65

VAPOR PRESSURES OF PURE SUBSTANCES Units Conversions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . AdditionalReferences . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Tables 2-3 Vapor Pressure of Water Ice from 0 to −40 °C . . . . . . . . . . . . 2-4 Vapor Pressure of Supercooled Liquid Water from 0 to −40 °C . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-5 Vapor Pressure (MPa) of Liquid Water from 0 to 100 °C . . . . . . . . . . . . . . . . . . . . . .. . . . . . . . . . . . . 2-6 Substances in Tables 2-8, 2-32, 2-141, 2-150, 2-153, 2-155, 2-156, 2-179, 2-312, 2-313, 2-314, and 2-315 Sorted by Chemical Family . . . . . . . . . . . . 2-7 Formula Index of Substances in Tables 2-8, 2-32, 2-141, 2-150, 2-153, 2-155, 2-156, 2-179, 2-312, 2-313, 2-314, and 2-315 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-8 Vapor Pressure of Inorganicand Organic Liquids, ln P = C1 + C2/T + C3 ln T + C4 T C5, P in Pa . . . . . . . . . . . . . 2-9 Vapor Pressures of Inorganic Compounds, up to 1 atm . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

2-48 2-48 2-48 2-48 2-48 2-49 2-52 2-55 2-61

VAPOR PRESSURES OF SOLUTIONS Units Conversions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . . . . . Tables 2-11 Partial Pressures of Water over Aqueous Solutions of HCl . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-12 Partial Pressures of HCl over Aqueous Solutions of HCl . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Vapor Pressures of H3PO4 Aqueous: Partial Pressure of H2O Vapor (Fig. 2-1) . . . . . . . .. . . . . . . . . . . . . . . . . . . . . . . Vapor Pressures of H3PO4 Aqueous: Weight of H2O in Saturated Air (Fig. 2-2) . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-13 Partial Pressures of H2O and SO2 over Aqueous Solutions of Sulfur Dioxide . . . . . . . . . . . . . . . . . . . . . . . . . 2-14 Water Partial Pressure, bar, over Aqueous Sulfuric Acid Solutions . . . . . . . . . . . .. . . . . . . . . . . . . . . . . . . . . . . . 2-15 Sulfur Trioxide Partial Pressure, bar, over Aqueous Sulfuric Acid Solutions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-16 Sulfuric Acid Partial Pressure, bar, over Aqueous Sulfuric Acid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-17 Total Pressure, bar, of Aqueous Sulfuric Acid Solutions . . . . .. 2-18 Partial Pressures of HNO3 and H2O over Aqueous Solutions of HNO3 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-19 Partial Pressures of H2O and HBr over Aqueous Solutions of HBr at 20 to 55 °C . . . . . . . . . . . . . . . . . . . . . .

2-80 2-80 2-80 2-81 2-81 2-81 2-82 2-84 2-86 2-87 2-88 2-89

*Contribution in part of the National Institute of Standards and...