Reacción de Simmons

Reacción de Simmons-Smith
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Reacción de Simmons-Smith

Reacción de Simmons-Smith en curso
La reacción de Simmons-Smith es una  HYPERLINK"http://translate.googleusercontent.com/translate_c?depth=1&hl=es&prev=/search%3Fq%3Dreaccion%2Bde%2Bsimon%2Bsmith%26biw%3D1517%26bih%3D677&rurl=translate.google.com.co&sl=en&u=http://en.wikipedia.org/wiki/Organic_reaction&usg=ALkJrhjk-FX-GM_JvspkM2SCTTWl8EPL9g" \o "Reacción orgánica" orgánica  HYPERLINK"http://translate.googleusercontent.com/translate_c?depth=1&hl=es&prev=/search%3Fq%3Dreaccion%2Bde%2Bsimon%2Bsmith%26biw%3D1517%26bih%3D677&rurl=translate.google.com.co&sl=en&u=http://en.wikipedia.org/wiki/Cheletropic_reaction&usg=ALkJrhhF1GTKqsvzFvg_wEO083OZI_NMvA" \o "Reacción Cheletropic" reacción cheletropic implica una  HYPERLINK "http://translate.googleusercontent.com/translate_c?depth=1&hl=es&prev=/search%3Fq%3Dreaccion%2Bde%2Bsimon%2Bsmith%26biw%3D1517%26bih%3D677&rurl=translate.google.com.co&sl=en&u=http://en.wikipedia.org/wiki/Organozinc_compound&usg=ALkJrhg3j76tNUsicNuADpvq4emG2gFNOA" \o "Compuestoorgánico de zinc" organozinc  HYPERLINK "http://translate.googleusercontent.com/translate_c?depth=1&hl=es&prev=/search%3Fq%3Dreaccion%2Bde%2Bsimon%2Bsmith%26biw%3D1517%26bih%3D677&rurl=translate.google.com.co&sl=en&u=http://en.wikipedia.org/wiki/Carbenoid&usg=ALkJrhiy4S_w4AL1wWIx-6sJmKbERuy9lA" \o "Carbenoide" carbenoide reacciona con unalqueno (o  HYPERLINK"http://translate.googleusercontent.com/translate_c?depth=1&hl=es&prev=/search%3Fq%3Dreaccion%2Bde%2Bsimon%2Bsmith%26biw%3D1517%26bih%3D677&rurl=translate.google.com.co&sl=en&u=http://en.wikipedia.org/wiki/Alkyne&usg=ALkJrhivzo9R0hWrYL0vPac49D_g9B1STQ" \o "Alkyne" alquino ) para formar un  HYPERLINK"http://translate.googleusercontent.com/translate_c?depth=1&hl=es&prev=/search%3Fq%3Dreaccion%2Bde%2Bsimon%2Bsmith%26biw%3D1517%26bih%3D677&rurl=translate.google.com.co&sl=en&u=http://en.wikipedia.org/wiki/Cyclopropane&usg=ALkJrhgNvs6USdHo7Jexxb4fp9dpVI8gKQ" \o "Ciclopropano" ciclopropano . [1] [2] [3] Es el nombre de Howard Ensign Simmons, Jr. y Ronald D. Smith. Se utiliza un  HYPERLINK"http://translate.googleusercontent.com/translate_c?depth=1&hl=es&prev=/search%3Fq%3Dreaccion%2Bde%2Bsimon%2Bsmith%26biw%3D1517%26bih%3D677&rurl=translate.google.com.co&sl=en&u=http://en.wikipedia.org/wiki/Methylene_radical&usg=ALkJrhiAYjkElNbT-C23zETHO-g0SiOkPw" \o "Radical metileno" metileno de radicales libres intermedio que se entrega a ambos carbonos del alqueno de forma simultánea, por lo tanto, la configuracióndel doble enlace se conserva en el producto y la reacción es estereoespecífica. [4]
Por lo tanto,  HYPERLINK "http://translate.googleusercontent.com/translate_c?depth=1&hl=es&prev=/search%3Fq%3Dreaccion%2Bde%2Bsimon%2Bsmith%26biw%3D1517%26bih%3D677&rurl=translate.google.com.co&sl=en&u=http://en.wikipedia.org/wiki/Cyclohexene&usg=ALkJrhjefIpbapbp3tlYJG-yfmFim61rlA"\o "Ciclohexeno" ciclohexeno ,  HYPERLINK "http://translate.googleusercontent.com/translate_c?depth=1&hl=es&prev=/search%3Fq%3Dreaccion%2Bde%2Bsimon%2Bsmith%26biw%3D1517%26bih%3D677&rurl=translate.google.com.co&sl=en&u=http://en.wikipedia.org/wiki/Diiodomethane&usg=ALkJrhi4J3Wdgv28vrAkM8s32IBRg8jA7Q" \o "Diyodometano" diyodometano , y un par de zinc-cobre (como HYPERLINK "http://translate.googleusercontent.com/translate_c?depth=1&hl=es&prev=/search%3Fq%3Dreaccion%2Bde%2Bsimon%2Bsmith%26biw%3D1517%26bih%3D677&rurl=translate.google.com.co&sl=en&u=http://en.wikipedia.org/wiki/Iodomethylzinc_iodide&usg=ALkJrhjpxdXAl47lTX0MvSm_R7Vvt4M6Wg" \o "Yoduro Iodomethylzinc" yoduro iodomethylzinc , ICH 2 Zni) rendimiento  HYPERLINK...