termodinamica



TERMODINÁMICA PARA LA INGENIERÍA
I. Usando los modelos Wilson y NRTL graficar P-X-Y



P(kPa)
X1
Y1
19.924
0
0
28.823
0.05
0.331
30.414
0.1
0.374
30.717
0.15
0.383
30.8110.2
0.387
30.894
0.25
0.391
30.985
0.3
0.397
31.064
0.35
0.405
31.11
0.4
0.415
30.104
0.45
0.428
31.029
0.5
0.443
30.869
0.55
0.461
30.608
0.6
0.481
30.226
0.65
0.50429.701
0.7
0.532
28.997
0.75
0.565
28.068
0.8
0.607
26.85
0.85
0.66
25.249
0.9
0.733
23.131
0.95
0.836
20.298
1
1















De la tabla tenemos:
P1 SAT=20.298
P2SAT =19.924

Mediante la ecuación:


P(kPa)
X1
Y1
γ1
X2
Y2
γ2
Lnγ1
Lnγ2
gE/RT
gE/X1*X2*RT
19.924
0
0
---
1
1
1
---
0
---
---
28.823
0.05
0.331
9.400347820.95
0.669
1.01874423
2.24074669
0.01857072
0.12967952
2.73009512
30.414
0.1
0.374
5.6039196
0.9
0.626
1.06176604
1.72346628
0.0599336
0.22628687
2.51429855
30.717
0.15
0.3833.86396394
0.85
0.617
1.11909899
1.35169358
0.11252389
0.29839934
2.34038699
30.811
0.2
0.387
2.93719997
0.8
0.613
1.18494924
1.07745674
0.16969994
0.3512513
2.19532063
30.894
0.250.391
2.38044221
0.75
0.609
1.25908091
0.86728627
0.23038202
0.38960808
2.07790976
30.985
0.3
0.397
2.02007505
0.7
0.603
1.33965892
0.70313466
0.29241504
0.41563093
1.9791949
31.0640.35
0.405
1.77088805
0.65
0.595
1.42719874
0.57148115
0.3557136
0.43123224
1.89552633
31.11
0.4
0.415
1.59013819
0.6
0.585
1.52239761
0.46382093
0.42028647
0.437700251.82375104
30.104
0.45
0.428
1.41059459
0.55
0.572
1.57137924
0.34401131
0.45195373
0.40337964
1.62981673
31.029
0.5
0.443
1.35440408
0.5
0.557
1.73490795
0.30336156
0.55095436
0.427157961.70863184
30.869
0.55
0.461
1.27469872
0.45
0.539
1.85576201
0.24270985
0.6182954
0.41172335
1.66352867
30.608
0.6
0.481
1.20885867
0.4
0.519
1.99326842
0.18967667
0.68977571...