Acido Acrilico

Chemical Engineering 140 October 29, 2007

Midterm Examination #2

(140) 1. Acrylic acid (C3H4O2) is formed via the oxidation of propylene (C3H6) in a two-step reaction asillustrated in Figure 1. Pure propylene (stream A) combines with a recycle stream (I) and enters the first reactor. Water and air in separate streams are fed into Reactor 1 as well. In the firstreactor, propylene reacts with oxygen to form acrolein (C3H4O). The effluent stream of the first reactor is then fed into the second reactor where acrolein is completely converted to acrylic acid.The effluent of the second reactor is fed to a separator where all of the water and the acrylic acid are removed in one stream to form a stream of 40 mol % acrylic acid. The remaining materialexits the reactor where 20% is purged and the rest is recycled back to the pure propylene feed. The composition of the purge stream (stream H) is 2.2% propylene, 10% oxygen and 87.8%nitrogen. The overall conversion of propylene is 80%.

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Figure 1: Process flow diagram for oxidation of propylene to form acrylic acid


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|(30) |How manymoles of water to moles of propylene fed into the system must be added in order to achieve 40 mol% acrylic acid in the |
| |product output from the separator?|
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|(30) |Calculate the molar recycle rate to the molar feed rate of pure propylene. |
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|(30) |What is the single pass conversion of Reactor 1?...