Apendices geankoplis
Páginas: 32 (7811 palabras)
Publicado: 22 de marzo de 2012
A.l-1. Constante R de la ley de los gases
Valor numérico 1.9872 1.9872 82.057 83 14.34 82.057 x 1 83 14.34 10.73 1 0.7302 1545.3 83 14.34
A.l-2 Volumen y demsidad mm de Hg = 22.4140 lt = 22414 mm3 1 g mal de gas ideal a 0 “G, 1 Ib mal de gas ideal a 0 “C, 1 kg mal de gas ideal a 0 “C, 76 Densidad del aire seco a 0 “C, 760 mm de Peso molecular del aire = 2 .w Ibmm mal = 2 1 @cm3 = 62.43lb,,$ie3 = 1000 kghn’ 1 g/cm3 = 8.345 lb,/gal ~su~~~~~~~~s~ 1 lb,/pie3 = 16.0185 kgimY
A.l-3. Longitud 1 pulg. = 2.540 cm 100 cm = 1 m
1 J = 1 N . m = 1 kg *m*,@ 1 kg . m*/s* = 1 J ($wBe) = 10’ g 0 cm%’ (er& 1 btu = 1055.06 J = B.05506 kJ 1 btu = 252.16 cal ~t~~~q~~~~~~~ 1 kcal (t~~~~~~~~~~~~ = B 1 cal (termoquímica) = 4. 1 1 1 1 1 1 btu = 251.996 cal (HT’) btu = 778.17 pie a Ibf hp . h =0.7457 k bp ~h = 2544.5 pie . Ibf= B-355 pie *Ibf/Pb, = 2
1 btu/h . pie . ‘F = 4.1365 x 10-j cd/s bcm ‘ “C 1 btu/b . pie 1“F = 1.73073 whl s K
1 1 1 1
btdh . pie* *‘F = 1.3571 x PO4 caLIs c ctd ~*C btuih *pie* . “F = 5.67 btdh . pie* . T = 5.6785 Wld * kcal/h *d . T = 0.2048 btdh . pie2 . “ F
btdlb, . “F = 4.1 Jkg * btdlb, . “F = 1.000 Cxnlig * T btdlb, = 2324.0 Jkg
283.15 293.15298.15 303.15 313.15
10 20 25 30 40
0. 0. 0.
0
O’.!ná83
273.15 275.15 277.15 279.15 281.15 283.15 285.15 287.15 289.15 291.15 293.15 293.35 295.15 297.15 298.15 299.15 301.15 303.15 305.15 307.15 309.15 311.15 313.15 315.15 317.15 319.15 321.15
0 2 4 6 8 10 12 14 16 18 20 20.2 22 24 25 26 28 30 32 34 36 38 40 42 44 46 48
1.7921 1.6728 1.5674 n .4?28 1.3860 1.3077 1.2363 1.1709l.B111 B.055 B.005 B.0000 0.9579
0.7679 0.7371
0.6087 0.5683
Nueva York. McGrsw-Mi, Baok
Referencia: Bingham, Flui&~ and Piasficity.
Company, 1922. Con autorización.
3 6 9 12 15 18 21 24 25 -27 30 33 36 40 45 50 55 60 65 70 75 80 85 90 95 100
Q.OP
3.169 3.567. 4.246 5.034
12.349
64-l 65 70 75 80 85 90 95 100 110 120 130 140 150 160 170 180 190 200 210 212 220 230 240270
.2563
0.OáQ035
120~6.9 ll82I.5 8657.7 739.7
28.8 33.8~9 38.0~ 43.6
1887.7 r@Ix&o 18’94.2
0.5073 0.8162
2.225 2.892 3.722 4.745 5.996 7.515 9.343 11.529 14.125 14.698 17.1 20.7 24.97 41.85
77.23 62.02 50.26 40.95 33.6’3 27.82
E27.96 137.97 v47.99
1130.1 în42.1 B 145,.9 1 n49.7 1158.5 1153.5’ 1157.1 ñ 1m.7 íá642 ll 147.6 1170.9 în74.1 á 1772 1 n 88’2 1183’,8 n15%.x8 I P33“T 1 l95.2 1 n97. n 199.0 IZO0.ó 12a2.0’
18Q.P6’ 208.4?4 2n8,59
340 350 360 370 380 390 400 4110
117.93 P34t.53 152.92 173.23 2.33’9 2.087 247.1 .5 P .&726
311.30 3’42%
1000
(179.91) s
H
1500 H (198.32) s
V
2000 (212.42) s
Apéndice A.2 Propiedades físicas del agua
A.2.11
Propiedades de transferencia de cakr del agpna Iíqnida
6)
273.2 288.8 2999311.0 338.8 366.5 394.3 422.1 477.6 533.2 588.8
121.1 148.9 204.4 260.0 315.6
943.5 917.9 858.6 784.9 679.2
4.271 4.312 4.522 4.982 6.322
0.1935 0.B384 O.PO42
O,á”36 0.6611 0.507l 1.07 31.5
é3010 223 n 5308
315.6 588.8 371.1 644.3 426.7 699.3
0. 0. 0.
APÉNDICE A.3
Propiedades Jisicas de compuestos inorgánicos y orgánicos
A.3-1
Calores estándar de formación a298.15 K (25 OC) y 101.325 kPa (1 atm abs), (c) = cristales, (g) = gas, (0 = líquido
mf Compuesto (?dkg mol)10-3 kcal/g mol Compuesto
CaCOj(c) CaO cwd
COZ@ CH&) C2H6(.d C3Kd.d CH3OWO
mf (kJlkg mol)l P3
-1206.87 -635.5 -110.523 -393.513 -74.848 -84.667 -103.847 -238.66 -277.61
kcal/g mol
-288.45 -151.9 -26.4157 -94.0518 -17.889 -20.236 -24.820 -57.04 -66.35
NW.d NOO
H2W Hz%9 HCW HCWH2S04(1) H3P04(c)
NaCl(c) NH4Cl(c)
-46.19 +90.374 -285.840 -241.826 +130.1 -92.3 12 -811.32 -1281.1 -411.003 -315.39
-11.04 +21.600 -68.3174 -57.7979 +31.1 -22.063 -193.91 -306.2 -98.232 -75.38
CH3CH30H(I)
Referencia: J. H. Peny y C. H. Chilton, Chemical Engineers’ Handbook, 5a. ed. Nueva York: McGraw-Hill, Book Company, 1973; y O.A. Hougen, K. M. Watson y R. A. Ragatz, Chemical...
Valor numérico 1.9872 1.9872 82.057 83 14.34 82.057 x 1 83 14.34 10.73 1 0.7302 1545.3 83 14.34
A.l-2 Volumen y demsidad mm de Hg = 22.4140 lt = 22414 mm3 1 g mal de gas ideal a 0 “G, 1 Ib mal de gas ideal a 0 “C, 1 kg mal de gas ideal a 0 “C, 76 Densidad del aire seco a 0 “C, 760 mm de Peso molecular del aire = 2 .w Ibmm mal = 2 1 @cm3 = 62.43lb,,$ie3 = 1000 kghn’ 1 g/cm3 = 8.345 lb,/gal ~su~~~~~~~~s~ 1 lb,/pie3 = 16.0185 kgimY
A.l-3. Longitud 1 pulg. = 2.540 cm 100 cm = 1 m
1 J = 1 N . m = 1 kg *m*,@ 1 kg . m*/s* = 1 J ($wBe) = 10’ g 0 cm%’ (er& 1 btu = 1055.06 J = B.05506 kJ 1 btu = 252.16 cal ~t~~~q~~~~~~~ 1 kcal (t~~~~~~~~~~~~ = B 1 cal (termoquímica) = 4. 1 1 1 1 1 1 btu = 251.996 cal (HT’) btu = 778.17 pie a Ibf hp . h =0.7457 k bp ~h = 2544.5 pie . Ibf= B-355 pie *Ibf/Pb, = 2
1 btu/h . pie . ‘F = 4.1365 x 10-j cd/s bcm ‘ “C 1 btu/b . pie 1“F = 1.73073 whl s K
1 1 1 1
btdh . pie* *‘F = 1.3571 x PO4 caLIs c ctd ~*C btuih *pie* . “F = 5.67 btdh . pie* . T = 5.6785 Wld * kcal/h *d . T = 0.2048 btdh . pie2 . “ F
btdlb, . “F = 4.1 Jkg * btdlb, . “F = 1.000 Cxnlig * T btdlb, = 2324.0 Jkg
283.15 293.15298.15 303.15 313.15
10 20 25 30 40
0. 0. 0.
0
O’.!ná83
273.15 275.15 277.15 279.15 281.15 283.15 285.15 287.15 289.15 291.15 293.15 293.35 295.15 297.15 298.15 299.15 301.15 303.15 305.15 307.15 309.15 311.15 313.15 315.15 317.15 319.15 321.15
0 2 4 6 8 10 12 14 16 18 20 20.2 22 24 25 26 28 30 32 34 36 38 40 42 44 46 48
1.7921 1.6728 1.5674 n .4?28 1.3860 1.3077 1.2363 1.1709l.B111 B.055 B.005 B.0000 0.9579
0.7679 0.7371
0.6087 0.5683
Nueva York. McGrsw-Mi, Baok
Referencia: Bingham, Flui&~ and Piasficity.
Company, 1922. Con autorización.
3 6 9 12 15 18 21 24 25 -27 30 33 36 40 45 50 55 60 65 70 75 80 85 90 95 100
Q.OP
3.169 3.567. 4.246 5.034
12.349
64-l 65 70 75 80 85 90 95 100 110 120 130 140 150 160 170 180 190 200 210 212 220 230 240270
.2563
0.OáQ035
120~6.9 ll82I.5 8657.7 739.7
28.8 33.8~9 38.0~ 43.6
1887.7 r@Ix&o 18’94.2
0.5073 0.8162
2.225 2.892 3.722 4.745 5.996 7.515 9.343 11.529 14.125 14.698 17.1 20.7 24.97 41.85
77.23 62.02 50.26 40.95 33.6’3 27.82
E27.96 137.97 v47.99
1130.1 în42.1 B 145,.9 1 n49.7 1158.5 1153.5’ 1157.1 ñ 1m.7 íá642 ll 147.6 1170.9 în74.1 á 1772 1 n 88’2 1183’,8 n15%.x8 I P33“T 1 l95.2 1 n97. n 199.0 IZO0.ó 12a2.0’
18Q.P6’ 208.4?4 2n8,59
340 350 360 370 380 390 400 4110
117.93 P34t.53 152.92 173.23 2.33’9 2.087 247.1 .5 P .&726
311.30 3’42%
1000
(179.91) s
H
1500 H (198.32) s
V
2000 (212.42) s
Apéndice A.2 Propiedades físicas del agua
A.2.11
Propiedades de transferencia de cakr del agpna Iíqnida
6)
273.2 288.8 2999311.0 338.8 366.5 394.3 422.1 477.6 533.2 588.8
121.1 148.9 204.4 260.0 315.6
943.5 917.9 858.6 784.9 679.2
4.271 4.312 4.522 4.982 6.322
0.1935 0.B384 O.PO42
O,á”36 0.6611 0.507l 1.07 31.5
é3010 223 n 5308
315.6 588.8 371.1 644.3 426.7 699.3
0. 0. 0.
APÉNDICE A.3
Propiedades Jisicas de compuestos inorgánicos y orgánicos
A.3-1
Calores estándar de formación a298.15 K (25 OC) y 101.325 kPa (1 atm abs), (c) = cristales, (g) = gas, (0 = líquido
mf Compuesto (?dkg mol)10-3 kcal/g mol Compuesto
CaCOj(c) CaO cwd
COZ@ CH&) C2H6(.d C3Kd.d CH3OWO
mf (kJlkg mol)l P3
-1206.87 -635.5 -110.523 -393.513 -74.848 -84.667 -103.847 -238.66 -277.61
kcal/g mol
-288.45 -151.9 -26.4157 -94.0518 -17.889 -20.236 -24.820 -57.04 -66.35
NW.d NOO
H2W Hz%9 HCW HCWH2S04(1) H3P04(c)
NaCl(c) NH4Cl(c)
-46.19 +90.374 -285.840 -241.826 +130.1 -92.3 12 -811.32 -1281.1 -411.003 -315.39
-11.04 +21.600 -68.3174 -57.7979 +31.1 -22.063 -193.91 -306.2 -98.232 -75.38
CH3CH30H(I)
Referencia: J. H. Peny y C. H. Chilton, Chemical Engineers’ Handbook, 5a. ed. Nueva York: McGraw-Hill, Book Company, 1973; y O.A. Hougen, K. M. Watson y R. A. Ragatz, Chemical...
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