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Technology of

FLUOROPOLYMERS
Second Edition

Technology of

FLUOROPOLYMERS
Second Edition

Jiri George Drobny

Boca Raton London New York

CRC Press is an imprint of the Taylor & Francis Group, an informa business

CRC Press Taylor & Francis Group 6000 Broken Sound Parkway NW, Suite 300 Boca Raton, FL 33487-2742 © 2009 by Taylor & Francis Group, LLC CRC Press is an imprint ofTaylor & Francis Group, an Informa business No claim to original U.S. Government works Printed in the United States of America on acid-free paper 10 9 8 7 6 5 4 3 2 1 International Standard Book Number-13: 978-1-4200-6317-2 (Hardcover) This book contains information obtained from authentic and highly regarded sources. Reasonable efforts have been made to publish reliable data and information, butthe author and publisher cannot assume responsibility for the validity of all materials or the consequences of their use. The authors and publishers have attempted to trace the copyright holders of all material reproduced in this publication and apologize to copyright holders if permission to publish in this form has not been obtained. If any copyright material has not been acknowledged pleasewrite and let us know so we may rectify in any future reprint. Except as permitted under U.S. Copyright Law, no part of this book may be reprinted, reproduced, transmitted, or utilized in any form by any electronic, mechanical, or other means, now known or hereafter invented, including photocopying, microfilming, and recording, or in any information storage or retrieval system, without writtenpermission from the publishers. For permission to photocopy or use material electronically from this work, please access www.copyright.com (http://www.copyright.com/) or contact the Copyright Clearance Center, Inc. (CCC), 222 Rosewood Drive, Danvers, MA 01923, 978-750-8400. CCC is a not-for-profit organization that provides licenses and registration for a variety of users. For organizations that havebeen granted a photocopy license by the CCC, a separate system of payment has been arranged. Trademark Notice: Product or corporate names may be trademarks or registered trademarks, and are used only for identification and explanation without intent to infringe. Library of Congress Cataloging-in-Publication Data Drobny, Jiri George. Technology of fluoropolymers / Jiri G. Drobny. -- 2nd ed. p. cm.Includes bibliographical references and index. ISBN 978-1-4200-6317-2 (alk. paper) 1. Fluoropolymers. I. Title. TP1180.F6D76 2009 668.4’238--dc22 Visit the Taylor & Francis Web site at http://www.taylorandfrancis.com and the CRC Press Web site at http://www.crcpress.com 2008032890

Dedication
To Joshua, Daniel, and Abigail

v

Contents
Preface to the First Edition.................................................................................... xiii Preface to the Second Edition .................................................................................. xv Acknowledgments ..................................................................................................xvii About the Author....................................................................................................xix Chapter 1 Chapter 2 2.1 Introduction ..........................................................................................1 Basic Chemistry of Fluoropolymers .....................................................7

2.2

2.3

2.4

2.5

2.6 2.7 2.8 2.9 2.10

Polytetrafluoroethylene...................................................................................7 2.1.1 Industrial Synthesis of Tetrafluoroethylene ........................................7 2.1.2 Properties of Tetrafluoroethylene .......................................................8 2.1.3 Uses of Tetrafluoroethylene ................................................................9 2.1.4 Polymerization of Tetrafluoroethylene ...............................................9 Fluorinated...
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