Introducción a la cinetica quimica

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An Introduction to Chemical Kinetics

An Introduction to Chemical Kinetics. Margaret Robson Wright # 2004 John Wiley & Sons, Ltd. ISBNs: 0-470-09058-8 (hbk) 0-470-09059-6 (pbk)

An Introduction to Chemical Kinetics

Margaret Robson Wright
Formerly of The University of St Andrews, UK

Copyright # 2004

John Wiley & Sons Ltd, The Atrium, Southern Gate, Chichester, West Sussex PO19 8SQ,England Telephone (+44) 1243 779777

Email (for orders and customer service enquiries): cs-books@wiley.co.uk Visit our Home Page on www.wileyeurope.com or www.wiley.com All Rights Reserved. No part of this publication may be reproduced, stored in a retrieval system or transmitted in any form or by any means, electronic, mechanical, photocopying, recording, scanning or otherwise, except underthe terms of the Copyright, Designs and Patents Act 1988 or under the terms of a licence issued by the Copyright Licensing Agency Ltd, 90 Tottenham Court Road, London W1T 4LP, UK, without the permission in writing of the Publisher. Requests to the Publisher should be addressed to the Permissions Department, John Wiley & Sons Ltd, The Atrium, Southern Gate, Chichester, West Sussex PO19 8SQ, England,or emailed to permreq@wiley.co.uk, or faxed to (+44) 1243 770620. This publication is designed to provide accurate and authoritative information in regard to the subject matter covered. It is sold on the understanding that the Publisher is not engaged in rendering professional services. If professional advice or other expert assistance is required, the services of a competent professional shouldbe sought. Other Wiley Editorial Offices John Wiley & Sons Inc., 111 River Street, Hoboken, NJ 07030, USA Jossey-Bass, 989 Market Street, San Francisco, CA 94103-1741, USA Wiley–VCH Verlag GmbH, Boschstrasse 12, D-69469 Weinheim, Germany John Wiley & Sons Australia Ltd, 33 Park Road, Milton, Queensland 4064, Australia John Wiley & Sons (Asia) Pte Ltd, 2 Clementi Loop # 02-01, Jin Xing Distripark,Singapore 129809 John Wiley & Sons Canada Ltd, 22 Worcester Road, Etobicoke, Ontario, Canada M9W 1L1 Wiley also publishes its books in a variety of electronic formats. Some content that appears in print may not be available in electronic books. Library of Congress Cataloging-in-Publication Data Wright, Margaret Robson. An introduction to chemical kinetics / Margaret Robson Wright. p. cm. Includesbibliographical references and index. ISBN 0-470-09058-8 (acid-free paper) – ISBN 0-470-09059-6 (pbk. : acid-free paper) 1. Chemical kinetics. I. Title. QD502.W75 2004 5410 .394–dc22 British Library Cataloguing in Publication Data A catalogue record for this book is available from the British Library ISBN 0 470 09058 8 hardback 0 470 09059 6 paperback 2004006062

Typeset in 10.5/13pt Times byThomson Press (India) Limited, New Delhi Printed and bound in Great Britain by TJ International Ltd., Padstow, Cornwall This book is printed on acid-free paper responsibly manufactured from sustainable forestry in which at least two trees are planted for each one used for paper production.

Dedicated with much love and affection to my mother, Anne (in memoriam), with deep gratitude for all herloving help, to her oldest and dearest friends, Nessie (in memoriam) and Dodo Gilchrist of Cumnock, who, by their love and faith in me, have always been a source of great encouragement to me, and last, but not least, to my own immediate family, my husband, Patrick, our children Anne, Edward and Andrew and our cats.

Contents
Preface List of Symbols xiii xvii

1 Introduction 2 ExperimentalProcedures
2.1 Detection, Identification and Estimation of Concentration of Species Present 2.1.1 Chromatographic techniques: liquid–liquid and gas–liquid chromatography 2.1.2 Mass spectrometry (MS) 2.1.3 Spectroscopic techniques 2.1.4 Lasers 2.1.5 Fluorescence 2.1.6 Spin resonance methods: nuclear magnetic resonance (NMR) 2.1.7 Spin resonance methods: electron spin resonance (ESR) 2.1.8 Photoelectron...
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